AIR PRODUCTS & CHEMICALS,INC. -- POLYVINYL ALCOHOL, GRANULAR -- 6810-00-264-9031
===================== Product Identification ===================== Product ID:POLYVINYL ALCOHOL, GRANULAR MSDS Date:01/01/1991 FSC:6810 NIIN:00-264-9031 === Responsible Party === Company Name:AIR PRODUCTS & CHEMICALS,INC. Address:RT 222 Box:2662 City:ALLENTOWN State:PA ZIP:18001 Country:US Info Phone Num:800-345-3148 Emergency Phone Num:800-523-9374 OR 215-481-4911 Preparer's Name:C.A.EISENHARD CAGE:00742 === Contractor Identification === Company Name:AIR PRODUCTS AND CHEMICALS INC Address:7201 HAMILTON BLVD Box:City:ALLENTOWN State:PA ZIP:18195-1501 Country:US Phone:800-345-3148/ 800-752-1597 CAGE:00742 Company Name:CHEMICAL COMMODITIES AGENCY, INC. Address:27447 PACIFIC STREET Box:City:HIGHLAND State:CA ZIP:92346-2640 Country:US Phone:909-864-2310 CAGE:60777 ============= Composition/Information on Ingredients ============= Ingred Name:POLYVINYL ALCOHOL CAS:9002-89-5 RTECS #:TR8100000 Fraction by Wt: >95.00% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD 50 >10,000 MG/KG RAT Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. MAY CAUSE IRRITATION. NO CHRONIC EFFECTS FROM OVEREXPOSURE ARE ANTICIPATED. Explanation of Carcinogenicity:IRAC: ANIMAL POSITIVE AND HUMAN INDEFINITE Effects of Overexposure:MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. MAY CAUSE IRRITATION. NO CHRONIC EFFECTS FROM OVEREXPOSURE ARE ANTICIPATED. Medical Cond Aggravated by Exposure:DUST MAY AGGRAVATE SYMPTOMS OF BRONCHITIS OR MAY PROVOKE ASTHMATIC RESPONSES IN PERSONS WITH ASTHMA WHO ARE SENSITIVE TO DUSTS. ======================= First Aid Measures ======================= First Aid:EYE: IMMEDIATELY FLUSH WITH RUNNING WATER FOR 15 MINUTES WHILE HOLDING EYELID. GET MEDICAL ATTENTION. SKIN: FLUSH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. INHALATION: MOVE TO FRESH AIR. IF I RRITATION PERSISTS, GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. INGESTION IS NOT CONSIDERED TO PRESENT A TOXICOLOGICAL EMERGENCY. GET MEDICAL ADVICE. ===================== Fire Fighting Measures ===================== Flash Point Method:OC Flash Point:175F,79C Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER, ALCOHOL OR POLYMER FOAM Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:EXPLOSION HAZARD IS SLIGHT, IN THE FORM OF DUST, WHEN EXPOSED TO FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS A ND HEAVY RUBBER GLOVES. Neutralizing Agent:NONE ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL DRY PLACE. AVOID GENERATING DUST IN THE AIR. AVOID BREATHING DUST. KEEP CONTAINER CLOSED. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR DUST. Ventilation:USE ONLY IN A CHEMICAL FUME HOOD. Protective Gloves:CHEMICAL RESISTANT GLOVES Eye Protection:SAFETY GOGGLES. Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. WEAR DISPOSABLE COVERALLS AND DISCARD THEM AFTER USE. Work Hygienic Practices:MINIMIZE BREATHING DUST. CLEANSE SKIN THOROUGHLY AFTER CONTACT, BEFORE BREAKS AND MEALS, AND AT THE END OF WORK PERIODS. Supplemental Safety and Health AVOID ALL CONTACT. ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:>200F,>93C Decomp Temp:Decomp Text:>200F,>93C Vapor Pres:NIL Vapor Density:4138 Spec Gravity:1.329 pH:4-8.4% Solubility in Water:SLIGHT Appearance and Odor:COLORLESS, AMPRPHOUS POWDER. NO ODOR Percent Volatiles by Volume:5.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:EXTREME HEAT, SPARKS, OPEN FLAMES. Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.