CITY CHEMICAL CORP. (FRMLY IN NEW YORK,NY) -- POTASSIUM HYDROXIDE PELLETS -- 6810-00-597-7150
===================== Product Identification ===================== Product ID:POTASSIUM HYDROXIDE PELLETS MSDS Date:09/19/1995 FSC:6810 NIIN:00-597-7150 === Responsible Party === Company Name:CITY CHEMICAL CORP. (FRMLY IN NEW YORK,NY) Address:100 HOBOKEN AVE City:JERSEY CITY State:NJ ZIP:07310 Country:US Info Phone Num:201-653-6900/FAX 201-653-4468 Emergency Phone Num:800-424-9300(CHEMTREC) CAGE:83628 === Contractor Identification === Company Name:CITY CHEMICAL CORPORATION Address:100 HOBOKEN AVE City:JERSEY CITY State:NJ ZIP:07310 Country:US Phone:201-653-6900/800-248-2436 CAGE:83628 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM HYDROXIDE (CERCLA) CAS:1310-58-3 RTECS #:TT2100000 Other REC Limits:NONE RECOMMENDED OSHA PEL:C 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED,INHAL,ABSORBED THRU SKIN.MATL EXTREMELY DESTRUCTIVE TO TISSUE OF MUC MEMBRANES,UPPER RESP TRACT,EYE,SKIN.INHAL MAY BE FATAL AS RESULT OF SPASM,INFLAMM/EDEMA OF LARYNX/BRONCHI,CHEM PNEUMONITIS,PULM EDEMA. Effects of Overexposure:MAY INCLUDE BURNING SENSATION,COUGHING,WHEEZING,LARYNGITIS,SHORTNESS OF BREATH,HEADACHE,NAUSEA,VOMITING. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:IN CASE OF CONTACT IMMED FLUSH EYE/SKIN W/COPIOUS AMTS OF WATER FOR @LEAST 15MINS WHILE REMOVING CONTAM CLOTH/SHOES.ASSURE ADEQUATE FLUSHING OF EYES BY SEPARATING EYELIDS W/FINGERS.INHAL:REMOVE TO FRE SH AIR.NOT BREATH GIVE ART RESP;DIFFI BREATH GIVE OXY.INGEST:WASH OUT MOUTH W/WATER PROVIDED PERSON IS CONSC.CALL PHYSICIAN IMMED.DISCARD CONTAMIN CLOTH/SHOES. ===================== Fire Fighting Measures ===================== Flash Point:NON-COMBUSTIBLE Autoignition Temp:Autoignition Temp Text:NP Lower Limits:NP Upper Limits:NP Extinguishing Media:USE EXTINGJISHING MEDIA APPROPRIATE TO SURRUOUNDING FIRE CONDITIONS.DO NOT USE WATER. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING TO PREVENT CONTACT W/SKIN/EYES.REACTS VIOLENTLY W/WATER. Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA.WEAR SCBA,RUBB BOOTS,HEAVY RUBB GLOVE.SWEEP UP,PLACE IN BAG & HOLD FOR WASTE DISPO.AVOID RAISING DUST.VENTILATE AREA & WASH SPILL SITE AFTER MATL PICKUP IS COMPLETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. HMIS:5% ACETIC ACID. ====================== Handling and Storage ====================== Handling and Storage Precautions:DANGER:UNDER FIRE CONDITIONS MATL WILL METL,FLOW.MOLTEN MATL RXS VIOLENTLY W/WATER,CAN RX W/AL,SN,ZN,THEIR ALLOYS TO GENERATE FLAMM/EXPLO H2 GAS. Other Precautions:CORROSIVE/TOXIC.KEEP TIGHTLY CLOSED.DON'T ALLOW CONTACT W/WATER.STORE IN COOL DRY PLACE.POTASSIUM HYDROXIDE RXS W/TRICHLOROETHYLENE TO FORM SPONT FLAMM DICHLOROACETYLENE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR. Ventilation:USE ONLY IN CHEMICAL FUME HOOD. Protective Gloves:CHEM-RESISTANT GLOVES. Eye Protection:SAF GOGG,FCSHIELD(8"MIN). Other Protective Equipment:OTHER PROTECTIVE CLOTHING.SAFETY SHOWER/EYE BATH. Work Hygienic Practices:DON'T BREATH DUST/GET IN EYE/SKIN/CLOTH.AVOID PROL/REP EXPO.WASH WELL AFT HNDLG. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:B1 Boiling Pt:B.P. Text:NP Melt/Freeze Pt:M.P/F.P Text:682F,361C Decomp Temp:Decomp Text:NP Vapor Pres:1 @719C Vapor Density:NP Spec Gravity:2.044 pH:NP Viscosity:NP Evaporation Rate & Reference:NP Solubility in Water:NP Appearance and Odor:SOLID. Percent Volatiles by Volume:NP Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS,AL,HALOGENS,NITRO CMPDS,ORG MATLS,ACID CHLORIDES&ANHYDRIDES,MG,CU,SN,ZN.METALS,WATER. Stability Condition to Avoid:DON'T HEAT >METL POINT.PROTECT FROM MOISTURE.ABSORBS CO2 FROM AIR.TXS VIOLENTLY W/WATER;GENERATES FLAMM/EXPLO H2 W/METAL Hazardous Decomposition Products:HYDROGEN GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT LICENSED PROFESSIONAL WASTE DISPO SERVICE TO DISPO OF THIS MATL.OBSERVE ALL FED/STATE/LOC ENVIRONMENTAL REGS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.