CIBA-GEIGY CORP AGRICULTURAL DIV -- PRINCEP 4L -- 6840-00F027607
===================== Product Identification ===================== Product ID:PRINCEP 4L MSDS Date:02/02/1989 FSC:6840 NIIN:00F027607 === Responsible Party === Company Name:CIBA-GEIGY CORP AGRICULTURAL DIV Address:410 SWING RD Box:18300 City:GREENSBORO State:NC ZIP:27419 Country:US Info Phone Num:800-334-9481/919-292-7100 Emergency Phone Num:800-888-8372/919-292-7100 CAGE:0267X === Contractor Identification === Company Name:CIBA-GEIGY CORP Address:4917 DAWN AVE Box:18300 City:EAST LANSING State:MI ZIP:48823-5605 Country:US Phone:517-351-5900 CAGE:0267X Company Name:CIBA-GEIGY CORP, AGRICULTURAL DIV. Address:410 SWING ROAD Box:18300 City:GREENSBORO State:NC ZIP:27419 Phone:800-888-8372 OR 800-334-9481 CAGE:8K340 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL, GLYCOL CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 7% Other REC Limits:10 MG/CUM OSHA PEL:50 PPM ACGIH TLV:C 127 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SIMAZINE Ingred Name:DUST,NUISANCE ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): >5000 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EXPOSURE TO PRINCEP 4L CAN IRRITATE EYES, SKIN, NOSE & THROAT. IF SWALLOWED, NAUSEA & VOMITING MAY OCCUR. Explanation of Carcinogenicity:NONE Effects of Overexposure:EXPOSURE TO PRINCEP 4L CAN IRRITATE EYES, SKIN, NOSE & THROAT. IF SWALLOWED, NAUSEA & VOMITING MAY OCCUR. ======================= First Aid Measures ======================= First Aid:INGESTION: IF CONSCIOUS, GIVE 1-2 GLASSES OF WATER TO DRINK & INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. EYES: RINSE W/PLENTY OF WATER. SKIN: WASH W/PLENTY OF SOAP & WATER, INCLUDIN G HAIR/UNDER FINGERNAILS. INHALATION: MOVE TO FRESH AIR. APPLY CPR IF NECESSARY. OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTE TO PHYSICIAN: THERE IS NO SPECIFIC ANTIDOTE IF INGESTED. (SEE SUPP) ===================== Fire Fighting Measures ===================== Flash Point:>200F Extinguishing Media:DRY CHEMICAL, FOAM/CO2 Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & SCBA. EVACUATE AREA. PREVENT USE OF CONTAMINATED BUILDINGS, AREA & EQUIPMENT UNTIL DECONTAMINATED. Unusual Fire/Explosion Hazard:PRINCEP 4L IS AN NFPA CLASS IIIB LIQUID. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. SMALL: COVER MATERIAL W/ABSORBENT. SWEEP UP & PLACE IN AN APPROVED CHEMICAL CONTAINER. WASH AREA W/WATER CONTAINING A STRONG DETERGENT. ABSORB W/PET LITTER/OTHER ABSORBENT. FLUSH AREA W/WATER. DON'T CONTAMINATE WATER SUPPLY ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A WELL VENTILATED, SECURE AREA, OUT OF REACH OF CHILDREN/DOMESTIC ANIMALS. DON'T STORE FOOD/BEVERAGES/TOBACCO PRODUCTS IN THE STRORAGE AREA. Other Precautions:PREVENT AREAS WHERE THERE IS A POTENTIAL FOR EXPOSURE TO THE MATERIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED DUST/PESTICIDE RESPIRATOR. Ventilation:REQUIRED Protective Gloves:RUBBER Eye Protection:CHEMICAL SAFETY GLASSES/GOGGLES Other Protective Equipment:RUBBER BOOTS, LONG-SLEEVED SHIRT, LONG PANTS & HAT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NOTE TO PHYSICIAN CONT'D: IF LARGE AMOUNTS ARE INGESTED & EMESIS HAS BEEN INADEQUATE, LAVAGE STOMACH. 5MG/KG OF ACTIVATEED CHARCOAL SUSPENSION CAN BE LEFT IN THE STOMACH TO ABSORB THE REMAINING TOXICA NT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F Vapor Pres:0 Spec Gravity:1.14 Solubility in Water:6.2 MG/1 Appearance and Odor:LIGHT TAN LIQUID, ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DON'T REUSE PRODUCT CONTAINERS. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.